Friday, August 29, 2014

Metal-organic frameworks based upon non-zeotype 4-connected topology

CATEGORY: MESOPOROUS METAL–ORGANIC FRAMEWORKS 
Metal-organic frameworks based upon non-zeotype 4-connected topology


Type
Journal Article
Author
Dong-Sheng Li
Author
Ya-Pan Wu
Author
Jun Zhao
Author
Jian Zhang
Author
Jack Y. Lu
URL
Volume
261
Pages
1-27
Publication
Coordination Chemistry Reviews
Date
February 15, 2014
Abstract
Understanding the basic correlations between the composition, physical properties and topology of the underlying nets is crucial to further design and successfully prepare for the functional metal-organic framework materials,. Authors focus on recent advances in metal-organic frameworks (MOFs) that possess more common non-zeotype 4-connected topological nets (such as sql, kag, nbo, lvt, cds, qtz, dia, lon, pts, etc.)
They discuss the synthetic strategies of non-zeotype 4-connected MOFs and their related properties. They emphasize how to establish basic design principles and synthetic methodology to construct the same topological MOFs with different functions using specifically designed organic linkers.

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