Wednesday, January 21, 2015

Quality Improvement of Heavy Gas Oil with Hydroprocessing



Type
Journal Article
Author
Zoltán Varga
Author
Zoltán Eller
URL
Free Full Text Full Text Source (Subscription or Fee):  http://www.pp.bme.hu/ch/article/view/7129
Volume
58
Issue
2
Pages
117-123
Publication
Periodica Polytechnica Chemical Engineering
Date
2014
Abstract
Quantity requirement for diesel fuel of low sulphur and aromatic content is increasing worldwide; meantime the quality of available crude oils has declined causing challenges in hydroprocessing of gas oils.

Results of quality improvement of heavy gas oil are presented, it was carried out in one stage on NiMo/Al2O3 catalyst and in two stages on NiMo/Al2O3 and PtPd/USY-zeolit catalysts. In one stage hydroprocessing sulphur and polyaromatic contents of the products  met the requirements of the standard only if strict process parameters were applied which resulted in operation problems and product loss, moreover the advantageous process parameters of hydrodesulphurization and hydrodearomatization did not coincide.
In two stages hydrotreating a partially hydrogenated product obtained on NiMo catalyst was further hydroprocessed on PtPd/USY at moderate process conditions. Results showed that the advantageous process parameters for reduction of sulphur and aromatics coincided. Quality parameters of products regarding to aromatics met not only the requirements of the standard but the stricter requirements of engine manufacturers also
.

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