In situ Analytical TEM of Asphaltene Formation and Aggregation from Crude Oil

CATEGORY: ASPHALTENE
In situ Analytical TEM of Asphaltene Formation and Aggregation from Crude Oil

Type	Journal Article
Author	Arne Janssen
Author	Nestor J. Zaluzec
URL	Free Full Text Source:  https://www.cambridge.org/core/journals/microscopy-and-microanalysis/article/in-situ-analytical-tem-of-asphaltene-formation-and-aggregation-from-crude-oil/DD858E10B6DD791DDF2F1B3E5A3D8C47
Volume	22
Issue	S3
Pages	796-797
Publication	Microscopy and Microanalysis
Date	2016/07
Abstract	Asphaltenes are aromatic hydrocarbons found in crude oils or carbonaceous materials . They are characterized by complex chemistry and their presence in crude oils impacts the oil properties. Phase changes, viscosity, and interfacial properties of crude oils are strongly affected by asphaltenes and, perhaps most importantly, they tend to clump together when exposed to changes in temperature and pressure, such as in pipelines pumping oil up out of underground reservoirs. It is this aggregation of the particles that makes asphaltenes such a problem. Once they have come together, they aggregate further and further until they begin to depose onto the walls of the pipe. This poses an obvious issue to oil production, not just in the primary pipelines that first transport the oil but also in the transportation of that oil and finally the refining of the oil. Therefore, preventing flocculation of asphaltene in crude oil is an important goal. Extensive research has been performed in the last years to study the molecular and colloidal structure of asphaltenes . Many models have been proposed [3] , however what is known as the Yen model and later the modified Yen model (also known as the Yen - Mullins model) is one of the longest enduring and most widely adopted models of asphaltene formation [4 ,5 ] . This model proposes that there are three stages to asphaltene aggregation, firstly the ~1.5 nm asphaltene molecule on its own; a cluster of arene rings with substituent alkanes around its edge. These asphaltenes then stack up into ~ 2nm nanoaggregates, a long and thin structure with the same alkane offshoots. These nanoaggregates then stick together to form what are known as the clusters of nanoaggregates . The clusters are most likely fractal, and the smallest size of clusters is ~6 nm. Depending of the instability of asphaltene s i n the crude oil , larger clusters with dimensions from ten s of nanometers to macroscopic scale can f o r m [5]. TEM images of asphaltene have already been obtained and used in asphaltene research to understand the mechanisms of flocculation, aggregation and precipitation [6] . However, the disadvantage is that the sample may be altered during the sample preparation. In situ analytical TEM has huge potential to permit direct observations of the oil emulsion system at the nm scale , without the requirement of sam ple pre - treatments, which may be able to have an affect of the structural and chemical evolution of the sample. Initial in situ TEM experiments of asphaltene formation an d aggregation were conducted in a FEI Talos F200X TEM operated at 200 keV using the Pr otochips Poseidon P210 analytical liquid cell holder. Crude oil with a nominal asphaltene content of 3.7% were mixed with heptane to initiate flocculation of the asphaltenes in the liquid in situ cell . Our first results providing novel insights into the mechanisms of asphaltene flocculation, aggregation in oil + heptane emulsion . Figure 1 shows t he further development of asphaltene coalescence of an agglomerate after 4 h in the oil + heptane emulsion and after 1 and 3 min under the electron beam. The aggregation process is driven by the initial formation of 10 - 20 nm spherical clusters . These clusters agglomerated into larger globular structures. The observed flocculation sequence follows the proposed Yen model. However, the size of the initial clusters is slightly larger compare d to the proposed model . The size of the aggregates and also the precipitation rate is likely to be influenced from the electron beam and will be further investigated.

A Comparative study of the chemical structure of asphaltenes from Algerian petroleum collected at different stages of extraction and processing

CATEGORY: ASPHALTENE
A Comparative study of the chemical structure of asphaltenes from Algerian petroleum collected at different stages of extraction and processing

Type	Journal Article
Author	Mortada Daaou
Author	Asma Larbi
URL	http://www.sciencedirect.com/science/article/pii/S0920410515302047
Volume	138
Pages	50-56
Publication	Journal of Petroleum Science and Engineering
Date	February 2016
Abstract	The chemical composition of crude oil, and hence its physicochemical properties, changes during extraction, transportation and treatment. Researchers characterized the asphaltene fraction of algerian petroleum collected at three stages of production, namely at the petroleum well, from deposits resulted after petroleum storage, and from the vacuum residuum obtained during the refining process. Characterization results revealed significant differences in chemical structure among the three sample types. The asphaltenes from the storage deposit are noticeably different with respect to the other two, exhibiting a higher polarity, a greater heteroatom content, and a lower aromaticity involving a smaller number of substituted aromatic structures. Such features must be taken into account when designing strategies to prevent precipitation throughout the production process.

Effect of dispersants on the kinetics of asphaltene settling using turbidity measurement method

CATEGORY: ASPHALTENE
Effect of dispersants on the kinetics of asphaltene settling using turbidity measurement method

Type	Journal Article
Author	M. M. Shadman
Author	M. Vafaie-Sefti
URL	http://dx.doi.org/10.1080/10916466.2016.1193519
Volume	34
Issue	14
Pages	1233-1239
Publication	Petroleum Science and Technology
Date	July 17, 2016
Abstract	Chemical control of asphaltene precipitation using dispersants and inhibitors of precipitation or solvents of asphaltene is common. While asphaltene in crude oil is stable under specific conditions, there is no assurance that the system will be stable and asphaltenes could be remaining in suspension state. Researchers studiued the kinetic effects of three dispersants on stabilization of asphaltene aggregates using the turbidity measurement method. Turbidity measurement showed as the dispersant strength rises, the turbidity of unstable sample containing dispersant less declines versus time. In order to carry out further studies on dispersants, the effect of dispersant on asphaltene particle size distribution was investigated. The results of asphaltene particle size distribution measurements showed that adding dispersant cause to decrease the volume percent of particles with medium diameter.