Monday, September 30, 2013

Role of macroporosity in macro-mesoporous red mud catalysts for slurry-phase hydrocracking of vacuum residue

CATEGORY: CATALYSIS
Applied Catalysis A: General, Available online 28 August 2013, In Press, Accepted Manuscript
Role of macroporosity in macro-mesoporous red mud catalysts for slurry-phase hydrocracking of vacuum residue
Chinh Nguyen-Huy (a), Viet Hung Pham (a), Do Kyoung Kim (b), Do-Woan Kim (b), Seung Hoon Oh (b), Jin Suk Chung (a), Eun Woo Shin (a)
Abstract
Researchers introduced macro-mesoporosity red mud (RM) using polystyrene and Pluronic F-127 as co-templates in to improve the catalytic performance of RM for slurry-phase hydrocracking of vacuum residue. They characterized the resulting macro-mesoporous red mud (Ma-RM) catalysts and applied them to the slurry-phase hydrocracking of vacuum residue at 490°C for 2 hours. Comparative reaction tests showed that Ma-RM exhibited better catalytic behavior for the VR hydrocracking compared to activated RM without macropores.
Ma-RM successfully suppressed coke formation and increased liquid yield in products distribution. The macroporous structure of Ma-RM was connected by mesopores containing active sites for hydrogenation. The presence of a macro-mesoporous structure enhanced hydrogenation over the catalysts.
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