Inorg. Chem., 2012, 51 (1), pp 572–576
Selective CO2 Adsorption in a Robust and
Water-Stable Porous Coordination Polymer with New Network Topology
Sanjog S. Nagarkar , Abhijeet K. Chaudhari , and
Sujit K. Ghosh *
sghosh@iiserpune.ac.in
Department of Chemistry, Indian Institute of Science Education and Research
(IISER), Pashan, Pune, Maharashtra 411021, India
Abstract
Describes solvothermal synthesis of a robust and
water-stable porous coordination polymer [Cd(NDC)0.5(PCA)]·Gx (1) (H2NDC =
2,6-napthalenedicarboxylic acid, HPCA = 4-pyridinecarboxylic acid, G = guest
molecules) with new network topology.
The compound has high selectivity in uptake of
CO2 over other gases (H2, O2, Ar, N2, and CH4). The framework is highly stable
in presence of water vapor even at 60 °C. The high CO2 selectivity over other
gases and water stability makes the compound promising candidate for industrial
postcombustion gas separation application.
Full Text Source (Subscription or Fee): http://pubs.acs.org/doi/abs/10.1021/ic202102m
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